Faculty Information - Masanobu Tsuchimoto

Office

Academic background

Present specialized field

Research activities

Works

（Last updated : 2025-03-24 13:43:00）

Masanobu Tsuchimoto
Center for Education (Faculty of Engineering), Faculty of Engineering

Graduate School of Engineering

Master's Program in Applied Chemistry, Graduate School of Engineering

Professor

■ Office

Shin-Narashino Campus, No.3 Building,1st floor chemistry 1st experimental laboratory

■ Academic background

1988/04～1992/03

, doctor of science

■ Present specialized field

Inorganic/coordination chemistry (Key Word：coordination chemistry, lanthanide complex, photochemistry, photoluminescence)

■ Research activities

1.	2010/02～	The Photofunctional Complexes Research Association, Japan
2.	2008/04～	The Rare Earth Society of Japan
3.	1988/04～	Japan Society of Coordination Chemistry
4.	1987/04～	The Chemical Society of Japan

■ Works

1.	Article	Investigation of nitro-nitrito photoisomerization: crystal structures of trans-{2,2'-[ethane-1,2-diylbis- (nitrilomethylidyne)]diphenolato}(pyridine/4-methylpyridine)nitrocobalt(III) Acta Crystallographica Section E E74,pp.1759-1763 (Collaboration) 2018/11
2.	Article	Investigation of nitro-nitrito photoisomerization: crystal structures of trans-bis(acetylacetonato-O,O') (pyridine/4-methyl-pyridine/3-hydroxypyridine) nitrocobalt(III) Acta Crystallographica Section E E74,pp.1637-1642 (Collaboration) 2018/10
3.	Article	Investigation of solid-state photochemical nitro-nitrito linkage isomerization: crystal structures of trans- bis(ethylenediamine)(isothiocyanato)nitrocobalt(III) salts: thiocyanate, chloride monohydrate, and perchlorate-thiocyanate(0.75/0.25) Acta Crystallographica Section E E74,pp.1526-1531 (Collaboration) 2018/10
4.	Article	Solvent dependence of the emission intensities in photoluminescentmononuclear europium(III) complexes with tetradentate Schiff base ligands Polyhedron 148,pp.118-123 (Collaboration) 2018/07
5.	Article	Luminescent DyIII single ion magnets with same N6O3 donor atoms but different donor atom arrangements, 'fac'-[Dy^III(HL^DL-ala)₃]8H₂O and 'mer'-[Dy^III(HL^DL-phe)₃]7H₂O polyhedron 109,pp.120-128 (Collaboration) 2016/04
6.	Article	Fluorescent and nonfluorescent crystals of N-(3,5-dihalogenosalicylidene)-2-methoxyaniline Journal of molecular structure 1105,pp.152-158 (Collaboration) 2016/02
7.	Article	Synthesis, crystal structure, luminescent and magnetic properties of europium(III) and terbium(III) complexes with a bidentate benzoate and a tripod N₇ ligand containing three imidazole, [Ln^III(H₃L)benzoate](ClO₄)₂ H₂O 2MeOH (Ln^III = Eu^III and Tb^III) Polyhedron 91,pp.28-34 (Collaboration) 2015/05
8.	Article	Synthesis, Structure, Luminescence, and Magnetic Properties of a Single-Ion Magnet "mer"-[Tris(N-[(imidazol-4-yl)-methylidene]-DL-phenylalaninato)terbium(III) and Related "fac"-DL-Alaninato Derivative Inorganic Chemistry 53(12),pp.5961-5971 (Collaboration) 2014/06
9.	Article	Synthesis, Structure, Luminescent, and Magnetic Properties of Carbonato-Bridged Zn^II₂Ln^III₂ Complexes [(u₄-CO₃)₂{Zn^IILⁿLn^III(NO₃)}₂] (Ln^III=Gd^III, Tb^III, Dy^III; L¹=N,N',-Bis(3-methoxy-2-oxybenzilidene)-1,3-propanediaminato) Inorganic Chemistry 52(21),pp.12828-12841 (Collaboration) 2013/11
10.	Article	Enantioselective aggregation and luminescence properties of europium(III) and terbium(III) complexes of an acetate and a tripodal ligand containing three imidazole groups Polyhedron 59,pp.76-84 (Collaboration) 2013/08
11.	Article	''Facial' and 'meridional' coordination geometries and luminescence properties of tris(N-[(imidazol-4-yl)methylidene]-DL-alaninato)europium(III) and tris(N-[(imidazol-4-yl)methylidene]-DL-phenylalaninato)europium(III) Polyhedron 49(1),pp.105-112 (Collaboration) 2013/01
12.	Article	Homo- and Heterochiral Aggregations of Samarium(III) Complexes with Acetate and Tripod Ligand Containing Three Imidazole Groups Bulletin of the Chemical Society of Japan 84(10),pp.1082-1089 (Collaboration) 2011/10
13.	Article	Luminescent europium(III) complexes of tripodal heptadentate N7 ligands containing three imidazole groups Polyhedron 30(15),pp.2026-2031 (Collaboration) 2011/09
14.	Article	Theoretical Study of Magnetic Properties of Oxovanadium(IV) Complex Self-Assemblies with Tetradentate Schiff Base Ligands Journal of physical chemistry B 115(26),pp.8465-8473 (Collaboration) 2011/07
15.	Article	Photoluminescence via Two Different Excited States in a Mononuclear Europium(III) Complex with Tetradentate Schiff Base Ligands Chemistry Letters 39(7),pp.706-707 (Collaboration) 2010/07
16.	Article	Synthesis and Electrochemical Properties of Oxovanadium Complexes with a Pentadentate Schiff Base Ligand Bulletin of the Chemical Society of Japan 77(10),pp.1849-1854 (Collaboration) 2004/10
17.	Article	Ferromagnetic Ni^II-Gd^III interactions in complexes with NiGd, NiGdNi, and NiGdGdNi cores supported by tripodal ligands Chemical Communications 2004(9),pp.1048-1049 (Collaboration) 2004/05
18.	Article	Synthesis and Crystal Structures of Polymeric and Dimeric Forms of an Oxotitanium(IV) Complex with a Tetradentate Schiff Base Ligand Bulletin of the Chemical Society of Japan 74(11),pp.2101-2105 (Single) 2001/10
19.	Article	Polymeric and Monomeric Forms of a Schiff Base-Nitridomanganese(V) Complex. Synthesis and Crystal Structure Chemistry Letters 2000(10),pp.1156-1157 (Collaboration) 2000/10
20.	Article	catena-Poly[[tetrakis(u-3,3-dimethylbutyrato-O:O')dicopper(II)] -u-3,3-dimethylbutyrato-O:O']-[bis(2,6-dimethylpyridine-N)copper(II)] -u-3,3-dimethylbutyrato-O:O'] and tetrakis(u-2,2-dimethylpropapnato-O:O')bis[(2,6-dimethylpyridine-N)copper(II)] Acta Crystallographica Section C C56(8),pp.e923-e925 (Collaboration) 2000/08
21.	Article	Mechanochemical Reaction of Polymeric Oxovanadium(IV) Complexes with Schiff BaseLigands Derived from 5-Nitrosalicylaldehyde and Diamines Journal of Solid State Chemistry 153(1),pp.9-15 (Collaboration) 2000/08
22.	Article	[1,2-Diphenyl-N,N'-bis(salicylidene)(RR,SS)- 1,2-ethanediyldiaminato]- nitridomanganese(V) Acta Crystallographica Section C C56(5),pp.e187 (Collaboration) 2000/05
23.	Article	[N,Nu-Bis(3-carboxysalicylidene)-1,2-diphenyl-(RR,SS)-1,2-ethanediyldiaminato-O,N,N',O'](methanol-O)oxovanadium(IV) and [N,N'-bis(3-carboxysalicylidene)-2,3-dimethyl-2,3-butanediyldiaminato-O,N,N',O']oxovanadium(IV) monohydrate Acta Crystallographica Section C 56(5),pp.e199-e2000 (Collaboration) 2000/05
24.	Article	exo-[N,N'-Bis(3-tert-butylsalicylidene)-1,2-diphenyl-(RS,SR)-1,2-ethanediaminato] oxovanadium(IV) Acta Crystallographica Section C C56(5),pp.e190 (Collaboration) 2000/05
25.	Article	Synthesis and Crystal Structure of Polymeric Oxovanadium(V) Complexes with Tetradentate Schiff Base Ligands Chemistry Letters 2000(5),pp.562-563 (Collaboration) 2000/05
26.	Article	Tetra-u-acetato-O:Ou-bis[(7-azaindole-N)copper(II)] Acta Crystallographica Section C C56(5),pp.e193 (Collaboration) 2000/05
27.	Article	The exo and endo isomers of [N,N'-bis(salicylidene)-1,2-diphenyl-(RS,SR)-1,2-ethanediaminato]oxovanadium(IV) Acta Crystallographica Section C 56(5),pp.e188-e189 (Collaboration) 2000/05
28.	Article	[N,N'-Bis(salicylidene)-1,2-diphenyl-(RS,SR)-1,2-ethanediaminato]nickel(II) Acta Crystallographica Section C C56(4),pp.e122 (Collaboration) 2000/04
29.	Article	catena-Poly[[tetrakis(u-2,2-dimethylpropionato-O:O')dicopper(II)]-u-dioxane-O:O'] and catena-poly-[[tetrakis(u-3,3-dimethylbutyrato-O:O')dicopper(II)]-u-dioxane-O,O'] Acta Crystallographica Section C C56(3),pp.e80-e81 (Collaboration) 2000/03
30.	Article	trans-Diaquabis(N-acetylanthranilato-O,O')copper(II) Acta Crystallographica Section C C56(3),pp.e79 (Collaboration) 2000/03
31.	Article	Thermal Dehydrogenation Reaction of [N,N'-Bis(3-ethoxysalicylidene)-1,2-diphenyl- 1,2-ethanediaminato]nickel(II) with [VO(salen)]NO₃ in the Solid State Bulletin of the Chemical Society of Japan 73(2),pp.369-374 (Collaboration) 2000/02
32.	Article	Dimeric copper(II) 3,3-dimethylbutyrate adducts with methanol, 2-methylpyridine, 3-methylpyridine, 4-methylpyridine and 3,3-dimethylbutyric acid Acta Crystallographica Section C C56(1),pp.7-11 (Collaboration) 2000/01
33.	Article	Dimeric copper(II) trimethylsilylacetate adducts with pyridine, 2-methylpyridine, 3-methylpyridine, and quinoline, and a polymeric copper(II) trimethylsilylacetate Acta Crystallographica Section C C56(1),pp.12-16 (Collaboration) 2000/01
34.	Article	[N,N'-Bis(5-methoxysalicylidene)-1,2-diphenyl-1,2-ethenediamine]oxovanadium(IV) Acta Crystallographica Section C C55(9),pp.1451-1453 (Collaboration) 1999/11
35.	Article	endo-{6,6'-Diethoxy-2,2'-[(R)-propane-1,2-diylbis(nitrilomethylidene)]diphenolato- O,N,N',O'}oxovanadium(IV) Acta Crystallographica Section C C55(11),pp.1812-1813 (Collaboration) 1999/11
36.	Article	Monomeric and polymeric structures of oxovanadium(IV) complexes with Schiff base ligands derived from (R,R)-2,4-pentanediamine Synthesis and crystal structure Polyhedron 18(23),pp.3035 (Collaboration) 1999/10
37.	Article	exo-[(RS,SR)-N,N'-Bis(salicylidene)-2,3-butanediaminato]oxovanadium(IV) Acta Crystallographica Section C C55(7),pp.1082-1084 (Collaboration) 1999/07
38.	Article	A monomeric and a dimeric copper(II) trigonelline adduct with chloride, and a dimeric copper(II) 1-methyl-2-pyrrole-carboxylate adduct with 3-methylpyridine Acta Crystallographica Section C C55(6),pp.882-886 (Collaboration) 1999/06
39.	Article	Molecular Rearrangement Accompanied by Solid-State Isomerization of {N,N'-Di-3-ethoxysalicylidene-(R,S)(S,R)-1,2-diphenyl-1,2-ethanediamine}oxovanadium(IV) Bulletin of the Chemical Society of Japan 72(5),pp.1037-1041 (Collaboration) 1999/05
40.	Article	(RS,SR)-N,N'-Bis(2-hydroxybenzyl)-1,2-diphenylethylenediamine Acta Crystallographica, Section C C55(4),pp.IUC9900030 (Collaboration) 1999/04
41.	Article	Copper(II) 2-thiopheneglyoxylate adducts with pyridine derivatives Acta Crystallographica, Section C C55(4),pp.592-594 (Collaboration) 1999/04
42.	Article	Redetermination of 2,3-dichloro-5,6-dicyano-1,4-dihydroxybenzene Acta Crystallographica, Section C C55(4),pp.592-594 (Collaboration) 1999/04
43.	Article	A dimeric copper(II) bis(4-chlorophenoxy)acetate adduct with dimethylformamide Acta Crystallographica, Section C C55(3),pp.316-318 (Collaboration) 1999/03
44.	Article	[N,N'-Bis(salicylidene)ethylenediamine](iso-thiocyanato)-oxovanadium(V) Acta Crystallographica Section C C55(2),pp.IUC9900008 (Collaboration) 1999/02
45.	Article	Magnetic properties of polynuclear oxovanadium(IV) complexes with tetradentate Schiff base ligands Chemical Physics Letters 297(1-2),pp.115-120 (Collaboration) 1998/11
46.	Article	Thermal Dehydrogenation of Oxovanadium(IV) Complexes with Schiff Base Ligands Derived from meso-1,2-Diphenyl-1,2-ethanediamine in the Solid State Inorganic Chemistry 37(1),pp.142-145 (Collaboration) 1998/01
47.	Article	trans-Bis(acetylacetonato)(3-methylpyridine)nitrocobalt(III) Acta Crystallographica, Section C C54(1),pp.46-47 (Collaboration) 1998/01
48.	Article	Structures and Magnetic Properties of Dimeric Copper(II) Benzoylformates Acta Crystallographica, Section B B53(4),pp.654-661 (Collaboration) 1997/10
49.	Article	Interconversion between Polymeric and Monomeric Forms of Oxovanadium(IV) Complexes with Tetradentate Schiff Base Ligands Derived from (R,R)-2,4-pentanediamine Inorganic Chemistry 35(26),pp.7661-7665 (Collaboration) 1996/12
50.	Article	Interconversion between Polymeric Orange and Monomeric Green Forms of a Schiff Base-Oxovanadium(IV) Complex Bulletin of the Chemical Society of Japan 69(11),pp.3207-3216 (Collaboration) 1996/11
51.	Article	Characterization of Monomeric Green and Polymeric Orange Forms of a Schiff Base- Oxovanadium(IV) Complex and Interconversion between These Species Proceedings of the Japan Academy, Series B 71(6),pp.175-178 (Collaboration) 1995/06
52.	Article	Synthesis and Characterization of trans-[CoCl₂(232N₄x)]⁺ (232N₄x=1,4,8,11-Tetraazacyclopentadecane,-cyclohexadecane, -cycloheptadecane, -cyclooctadecane, -cyclononadecane, -cycloicosane, cyclohenicosane, and -cyclotricosane) Bulletin of the Chemical Society of Japan 68(3),pp.866-873 (Collaboration) 1995/03
53.	Article	Isomerization of a Diastereomeric Oxovanadium(IV) Complex Containing an Unsymmetrical Tetradentate Schiff Base Ligand Catalyzed by Oxovanadium(V) Species Chemistry Letters 1994(9),pp.1593-1596 (Collaboration) 1994/09
54.	Article	Green and Orange Crystalline Forms of [VO{N-salicylidene-N'-3-ethoxysalicylidene- (R,R)-1,2-cyclohexanediamine}], Separation of the Diastereomeric Pair, and Isomerization between Them in the Solid State Chemistry Letters 1994(5),pp.949-952 (Collaboration) 1994/05
55.	Article	X-ray Structural Study of trans-[CoCl₂(N₄15)]⁺ (N₄15=1,4,7,10-Tetraazacyclotricosane) Bulletin of the Chemical Society of Japan 65(8),pp.2114-2117 (Collaboration) 1992/08
56.	Article	Synthesis and Characterization of trans-[CoCl₂(N₄x)]⁺ (N₄x=1,4,7,10-Tetraazacycloheptadecane, -cyclooctadecane, -cyclononadecane,-cycloicosane, -cycloicosane, -cyclohenicosane, and -cyclodocosane) Bulletin of the Chemical Society of Japan 65(1),pp.191-197 (Collaboration) 1992/01
57.	Article	Preparation and X-Ray Crystal Structure of trans-Dinitro(1,4,7,10-teteraazacycloheptadecane)cobalt(III) Tetrafluoroborate, trans-[Co(NO₂)₂(N₄10)]BF₄ Bulletin of the Chemical Society of Japan 64(8),pp.2554-2556 (Collaboration) 1991/08
58.	Article	Splitting of the 2nd d-d Band of trans-[CoCl₂N₄X]-Type Complexes Observed in the Solid State at 113 K Bulletin of the Chemical Society of Japan 63(12),pp.2410-3413 (Collaboration) 1990/12
59.	Article	X-Ray Structural Studies of Green and Brown Crystals of trans-[CoCl₂(N₄8)]X (N₄8= 1,4,7,10-Tetraazacyclopentadecane, X=NO₃^-, BF₄^-, and ClO₄^-) Bulletin of the Chemical Society of Japan 63(3),pp.785-791 (Collaboration) 1990/03
60.	Article	Synthesis and Chracterization of Co(III) Complexes with 1,4,7,10-Tetraazacyclotetradecane, -pentadecane, and -hexadecane Bulletin of the Chemical Society of Japan 63(1),pp.227-234 (Collaboration) 1990/01
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