■ 研究室
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■ 学位
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1988/04～1992/03
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名古屋大学大学院理学研究科化学専攻 博士（理学）
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■ 研究概要
・シッフ塩基を配位子とする単核の希土類錯体の発光特性
・エキシマ発光、室温りん光発光する希土類錯体
・サーモクロミズム、メカノクロミズムを示す金属錯体
など、発光やクロミズムなどの性質を示す金属錯体を中心として、光と色に関連する化合物の研究を行っています。
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■ 専門分野
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無機・錯体化学 （キーワード：錯体化学、希土類錯体、光化学、発光）
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■ 産学連携テーマ
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シッフ塩基を配位子とする発光性希土類錯体の開発に重点を置いている。希土類錯体の合成や発光特性などの基礎的な研究だけでなく、光学材料としての応用面にも注目している。
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■ 所属学会
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1.
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2010/02～
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複合系の光機能研究会
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2.
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2008/04～
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日本希土類学会
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3.
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1988/04～
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錯体化学会
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4.
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1987/04～
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日本化学会
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■ 著書・論文・作品
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1.
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論文
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Investigation of nitro-nitrito photoisomerization: crystal structures of trans-{2,2'-[ethane-1,2-diylbis- (nitrilomethylidyne)]diphenolato}(pyridine/4-methylpyridine)nitrocobalt(III) Acta Crystallographica Section E E74,pp.1759-1763 （共著） 2018/11
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2.
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論文
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Investigation of nitro-nitrito photoisomerization: crystal structures of trans-bis(acetylacetonato-O,O')
(pyridine/4-methyl-pyridine/3-hydroxypyridine) nitrocobalt(III) Acta Crystallographica Section E E74,pp.1637-1642 （共著） 2018/10
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3.
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論文
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Investigation of solid-state photochemical nitro-nitrito linkage isomerization: crystal structures of trans-
bis(ethylenediamine)(isothiocyanato)nitrocobalt(III) salts: thiocyanate, chloride monohydrate, and perchlorate-thiocyanate(0.75/0.25) Acta Crystallographica Section E E74,pp.1526-1531 （共著） 2018/10
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4.
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論文
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Solvent dependence of the emission intensities in photoluminescentmononuclear europium(III) complexes with tetradentate Schiff base ligands Polyhedron 148,pp.118-123 （共著） 2018/07
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5.
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論文
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Luminescent DyIII single ion magnets with same N6O3 donor atoms
but different donor atom arrangements, 'fac'-[DyIII(HLDL-ala)3]8H2O
and 'mer'-[DyIII(HLDL-phe)3]7H2O polyhedron 109,pp.120-128 （共著） 2016/04
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6.
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論文
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Fluorescent and nonfluorescent crystals of N-(3,5-dihalogenosalicylidene)-2-methoxyaniline Journal of molecular structure 1105,pp.152-158 （共著） 2016/02
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7.
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論文
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Synthesis, crystal structure, luminescent and magnetic properties of europium(III) and terbium(III) complexes with a bidentate benzoate and a tripod N7 ligand containing three imidazole,
[LnIII(H3L)benzoate](ClO4)2 H2O 2MeOH (LnIII = EuIII and TbIII) Polyhedron 91,pp.28-34 （共著） 2015/05
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8.
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論文
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Synthesis, Structure, Luminescence, and Magnetic Properties of a Single-Ion Magnet "mer"-[Tris(N-[(imidazol-4-yl)-methylidene]-DL-phenylalaninato)terbium(III) and Related "fac"-DL-Alaninato Derivative Inorganic Chemistry 53(12),pp.5961-5971 （共著） 2014/06
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9.
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論文
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Synthesis, Structure, Luminescent, and Magnetic Properties of Carbonato-Bridged ZnII2LnIII2 Complexes [(u4-CO3)2{ZnIILnLnIII(NO3)}2] (LnIII=GdIII, TbIII, DyIII; L1=N,N',-Bis(3-methoxy-2-oxybenzilidene)-1,3-propanediaminato) Inorganic Chemistry 52(21),pp.12828-12841 （共著） 2013/11
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10.
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論文
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Enantioselective aggregation and luminescence properties of europium(III) and terbium(III) complexes of an acetate and a tripodal ligand containing three imidazole groups Polyhedron 59,pp.76-84 （共著） 2013/08
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11.
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論文
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''Facial' and 'meridional' coordination geometries and luminescence properties of tris(N-[(imidazol-4-yl)methylidene]-DL-alaninato)europium(III) and tris(N-[(imidazol-4-yl)methylidene]-DL-phenylalaninato)europium(III) Polyhedron 49(1),pp.105-112 （共著） 2013/01
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12.
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論文
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Homo- and Heterochiral Aggregations of Samarium(III) Complexes with Acetate and Tripod Ligand Containing Three Imidazole Groups Bulletin of the Chemical Society of Japan 84(10),pp.1082-1089 （共著） 2011/10
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13.
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論文
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Luminescent europium(III) complexes of tripodal heptadentate N7 ligands containing three imidazole groups Polyhedron 30(15),pp.2026-2031 （共著） 2011/09
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14.
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論文
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Theoretical Study of Magnetic Properties of Oxovanadium(IV) Complex Self-Assemblies with Tetradentate Schiff Base Ligands Journal of physical chemistry B 115(26),pp.8465-8473 （共著） 2011/07
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15.
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論文
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Photoluminescence via Two Different Excited States in a Mononuclear Europium(III) Complex with Tetradentate Schiff Base Ligands Chemistry Letters 39(7),pp.706-707 （共著） 2010/07
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16.
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論文
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Synthesis and Structures of Vanadium-Cerium Trinuclear Complexes with Schiff Base Ligands Bulletin of the Chemical Society of Japan 79(9),1393-1397頁 （共著） 2006/09
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17.
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論文
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Synthesis and Electrochemical Properties of Oxovanadium Complexes with a Pentadentate Schiff Base Ligand Bulletin of the Chemical Society of Japan 77(10),pp.1849-1854 （共著） 2004/10
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18.
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論文
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Ferromagnetic NiII-GdIII interactions in complexes with NiGd, NiGdNi, and NiGdGdNi cores supported by tripodal ligands Chemical Communications 2004(9),pp.1048-1049 （共著） 2004/05
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19.
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論文
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Tetradentate Schiff base-oxovanadium(IV) complexes: structures and reactivities in the solid state Coordination Chemistry Reviews 237(1-2),183頁 （共著） 2003/02
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20.
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論文
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Synthesis and Crystal Structures of Polymeric and Dimeric Forms of an Oxotitanium(IV) Complex with a Tetradentate Schiff Base Ligand Bulletin of the Chemical Society of Japan 74(11),pp.2101-2105 （単著） 2001/10
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21.
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論文
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Synthesis and Magnetic Properties of a Polymeric Nitridochromium(V) Complex with a Tetradentate Schiff Base Ligand Europian Journal of Inorganic Chemistry 2001(4),1045-1049頁 （共著） 2001/04
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22.
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論文
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Oxygen Atom Exchange Reaction between Tetradentate Schiff Base-Oxovanadium(IV) Complexes and Water Bulletin of the Chemical Society of Japan 73(１０),2317-2323頁 （共著） 2000/10
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23.
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論文
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Polymeric and Monomeric Forms of a Schiff Base-Nitridomanganese(V) Complex. Synthesis and Crystal Structure Chemistry Letters 2000(10),pp.1156-1157 （共著） 2000/10
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24.
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論文
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catena-Poly[[tetrakis(u-3,3-dimethylbutyrato-O:O')dicopper(II)] -u-3,3-dimethylbutyrato-O:O']-[bis(2,6-dimethylpyridine-N)copper(II)] -u-3,3-dimethylbutyrato-O:O'] and tetrakis(u-2,2-dimethylpropapnato-O:O')bis[(2,6-dimethylpyridine-N)copper(II)] Acta Crystallographica Section C C56(8),pp.e923-e925 （共著） 2000/08
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25.
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論文
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Mechanochemical Reaction of Polymeric Oxovanadium(IV) Complexes with Schiff BaseLigands Derived from 5-Nitrosalicylaldehyde and Diamines Journal of Solid State Chemistry 153(1),pp.9-15 （共著） 2000/08
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26.
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論文
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[1,2-Diphenyl-N,N'-bis(salicylidene)(RR,SS)-
1,2-ethanediyldiaminato]- nitridomanganese(V) Acta Crystallographica Section C C56(5),pp.e187 （共著） 2000/05
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27.
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論文
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[N,Nu-Bis(3-carboxysalicylidene)-1,2-diphenyl-(RR,SS)-1,2-ethanediyldiaminato-O,N,N',O'](methanol-O)oxovanadium(IV) and [N,N'-bis(3-carboxysalicylidene)-2,3-dimethyl-2,3-butanediyldiaminato-O,N,N',O']oxovanadium(IV) monohydrate Acta Crystallographica Section C 56(5),pp.e199-e2000 （共著） 2000/05
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28.
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論文
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exo-[N,N'-Bis(3-tert-butylsalicylidene)-1,2-diphenyl-(RS,SR)-1,2-ethanediaminato] oxovanadium(IV) Acta Crystallographica Section C C56(5),pp.e190 （共著） 2000/05
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29.
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論文
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Synthesis and Crystal Structure of Polymeric Oxovanadium(V) Complexes with Tetradentate Schiff Base Ligands Chemistry Letters 2000(5),pp.562-563 （共著） 2000/05
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30.
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論文
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Tetra-u-acetato-O:Ou-bis[(7-azaindole-N)copper(II)] Acta Crystallographica Section C C56(5),pp.e193 （共著） 2000/05
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31.
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論文
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The exo and endo isomers of [N,N'-bis(salicylidene)-1,2-diphenyl-(RS,SR)-1,2-ethanediaminato]oxovanadium(IV) Acta Crystallographica Section C 56(5),pp.e188-e189 （共著） 2000/05
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32.
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論文
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[N,N'-Bis(salicylidene)-1,2-diphenyl-(RS,SR)-1,2-ethanediaminato]nickel(II) Acta Crystallographica Section C C56(4),pp.e122 （共著） 2000/04
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33.
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論文
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catena-Poly[[tetrakis(u-2,2-dimethylpropionato-O:O')dicopper(II)]-u-dioxane-O:O'] and catena-poly-[[tetrakis(u-3,3-dimethylbutyrato-O:O')dicopper(II)]-u-dioxane-O,O'] Acta Crystallographica Section C C56(3),pp.e80-e81 （共著） 2000/03
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34.
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論文
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trans-Diaquabis(N-acetylanthranilato-O,O')copper(II) Acta Crystallographica Section C C56(3),pp.e79 （共著） 2000/03
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35.
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論文
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Thermal Dehydrogenation Reaction of [N,N'-Bis(3-ethoxysalicylidene)-1,2-diphenyl-
1,2-ethanediaminato]nickel(II) with [VO(salen)]NO3 in the Solid State Bulletin of the Chemical Society of Japan 73(2),pp.369-374 （共著） 2000/02
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36.
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論文
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Dimeric copper(II) 3,3-dimethylbutyrate adducts with methanol, 2-methylpyridine, 3-methylpyridine, 4-methylpyridine and 3,3-dimethylbutyric acid Acta Crystallographica Section C C56(1),pp.7-11 （共著） 2000/01
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37.
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論文
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Dimeric copper(II) trimethylsilylacetate adducts with pyridine, 2-methylpyridine, 3-methylpyridine, and quinoline, and a polymeric copper(II) trimethylsilylacetate Acta Crystallographica Section C C56(1),pp.12-16 （共著） 2000/01
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38.
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論文
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[N,N'-Bis(5-methoxysalicylidene)-1,2-diphenyl-1,2-ethenediamine]oxovanadium(IV) Acta Crystallographica Section C C55(9),pp.1451-1453 （共著） 1999/11
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39.
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論文
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endo-{6,6'-Diethoxy-2,2'-[(R)-propane-1,2-diylbis(nitrilomethylidene)]diphenolato-
O,N,N',O'}oxovanadium(IV) Acta Crystallographica Section C C55(11),pp.1812-1813 （共著） 1999/11
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40.
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論文
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Monomeric and polymeric structures of oxovanadium(IV) complexes with Schiff base
ligands derived from (R,R)-2,4-pentanediamine Synthesis and crystal structure Polyhedron 18(23),pp.3035 （共著） 1999/10
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41.
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論文
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exo-[(RS,SR)-N,N'-Bis(salicylidene)-2,3-butanediaminato]oxovanadium(IV) Acta Crystallographica Section C C55(7),pp.1082-1084 （共著） 1999/07
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42.
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論文
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A monomeric and a dimeric copper(II) trigonelline adduct with chloride, and a dimeric copper(II) 1-methyl-2-pyrrole-carboxylate adduct with 3-methylpyridine Acta Crystallographica Section C C55(6),pp.882-886 （共著） 1999/06
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43.
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論文
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Molecular Rearrangement Accompanied by Solid-State Isomerization of {N,N'-Di-3-ethoxysalicylidene-(R,S)(S,R)-1,2-diphenyl-1,2-ethanediamine}oxovanadium(IV) Bulletin of the Chemical Society of Japan 72(5),pp.1037-1041 （共著） 1999/05
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44.
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論文
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(RS,SR)-N,N'-Bis(2-hydroxybenzyl)-1,2-diphenylethylenediamine Acta Crystallographica, Section C C55(4),pp.IUC9900030 （共著） 1999/04
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45.
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論文
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Copper(II) 2-thiopheneglyoxylate adducts with pyridine derivatives Acta Crystallographica, Section C C55(4),pp.592-594 （共著） 1999/04
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46.
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論文
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Redetermination of 2,3-dichloro-5,6-dicyano-1,4-dihydroxybenzene Acta Crystallographica, Section C C55(4),pp.592-594 （共著） 1999/04
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47.
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論文
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A dimeric copper(II) bis(4-chlorophenoxy)acetate adduct with dimethylformamide Acta Crystallographica, Section C C55(3),pp.316-318 （共著） 1999/03
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48.
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論文
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[N,N'-Bis(salicylidene)ethylenediamine](iso-thiocyanato)-oxovanadium(V) Acta Crystallographica Section C C55(2),pp.IUC9900008 （共著） 1999/02
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49.
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論文
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Magnetic properties of polynuclear oxovanadium(IV) complexes with tetradentate Schiff base ligands Chemical Physics Letters 297(1-2),pp.115-120 （共著） 1998/11
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50.
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論文
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Thermal Dehydrogenation of Oxovanadium(IV) Complexes with Schiff Base Ligands Derived from meso-1,2-Diphenyl-1,2-ethanediamine in the Solid State Inorganic Chemistry 37(1),pp.142-145 （共著） 1998/01
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51.
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論文
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trans-Bis(acetylacetonato)(3-methylpyridine)nitrocobalt(III) Acta Crystallographica, Section C C54(1),pp.46-47 （共著） 1998/01
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52.
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論文
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Structures and Magnetic Properties of Dimeric Copper(II) Benzoylformates Acta Crystallographica, Section B B53(4),pp.654-661 （共著） 1997/10
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53.
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論文
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Interconversion between Polymeric and Monomeric Forms of Oxovanadium(IV) Complexes with Tetradentate Schiff Base Ligands Derived from (R,R)-2,4-pentanediamine Inorganic Chemistry 35(26),pp.7661-7665 （共著） 1996/12
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54.
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論文
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Interconversion between Polymeric Orange and Monomeric Green Forms of a Schiff Base-Oxovanadium(IV) Complex Bulletin of the Chemical Society of Japan 69(11),pp.3207-3216 （共著） 1996/11
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55.
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論文
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Characterization of Monomeric Green and Polymeric Orange Forms of a Schiff Base- Oxovanadium(IV) Complex and Interconversion between These Species Proceedings of the Japan Academy, Series B 71(6),pp.175-178 （共著） 1995/06
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56.
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論文
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Synthesis and Characterization of trans-[CoCl2(232N4x)]+ (232N4x=1,4,8,11-Tetraazacyclopentadecane,-cyclohexadecane, -cycloheptadecane, -cyclooctadecane, -cyclononadecane, -cycloicosane, cyclohenicosane, and -cyclotricosane) Bulletin of the Chemical Society of Japan 68(3),pp.866-873 （共著） 1995/03
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57.
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論文
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Isomerization of a Diastereomeric Oxovanadium(IV) Complex Containing an Unsymmetrical Tetradentate Schiff Base Ligand Catalyzed by Oxovanadium(V) Species Chemistry Letters 1994(9),pp.1593-1596 （共著） 1994/09
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58.
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論文
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Green and Orange Crystalline Forms of [VO{N-salicylidene-N'-3-ethoxysalicylidene-
(R,R)-1,2-cyclohexanediamine}], Separation of the Diastereomeric Pair, and Isomerization between Them in the Solid State Chemistry Letters 1994(5),pp.949-952 （共著） 1994/05
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59.
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論文
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X-ray Structural Study of trans-[CoCl2(N415)]+ (N415=1,4,7,10-Tetraazacyclotricosane) Bulletin of the Chemical Society of Japan 65(8),pp.2114-2117 （共著） 1992/08
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60.
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論文
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Synthesis and Characterization of trans-[CoCl2(N4x)]+ (N4x=1,4,7,10-Tetraazacycloheptadecane, -cyclooctadecane, -cyclononadecane,-cycloicosane, -cycloicosane, -cyclohenicosane, and -cyclodocosane) Bulletin of the Chemical Society of Japan 65(1),pp.191-197 （共著） 1992/01
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61.
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論文
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Preparation and X-Ray Crystal Structure of trans-Dinitro(1,4,7,10-teteraazacycloheptadecane)cobalt(III) Tetrafluoroborate, trans-[Co(NO2)2(N410)]BF4 Bulletin of the Chemical Society of Japan 64(8),pp.2554-2556 （共著） 1991/08
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62.
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論文
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Splitting of the 2nd d-d Band of trans-[CoCl2N4X]-Type Complexes Observed in the Solid State at 113 K Bulletin of the Chemical Society of Japan 63(12),pp.2410-3413 （共著） 1990/12
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63.
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論文
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X-Ray Structural Studies of Green and Brown Crystals of trans-[CoCl2(N48)]X (N48= 1,4,7,10-Tetraazacyclopentadecane, X=NO3-, BF4-, and ClO4-) Bulletin of the Chemical Society of Japan 63(3),pp.785-791 （共著） 1990/03
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64.
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論文
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Synthesis and Chracterization of Co(III) Complexes with 1,4,7,10-Tetraazacyclotetradecane, -pentadecane, and -hexadecane Bulletin of the Chemical Society of Japan 63(1),pp.227-234 （共著） 1990/01
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5件表示
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全件表示(64件)
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■ 研究題目
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