イケダ マリ
Mari Ikeda
池田 茉莉 所属 千葉工業大学 工学部 教育センター(工学部) 職種 教授 |
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言語種別 | 英語 |
発行・発表の年月 | 2020/09 |
形態種別 | 学術雑誌 |
査読 | 査読あり |
標題 | Pentacyclic Nano-Trefoil |
執筆形態 | 共著 |
掲載誌名 | Angewandte Chemie International Edition |
掲載区分 | 国外 |
出版社・発行元 | WILEY-VCH VERLAG GMBH |
著者・共著者 | Ju Huiyeong, Tsuruoka Yumiko, Hyano Miho, Lee Eunji, Park Ki-Min, Ikeda Mari, Ishii Jun-Ichi, Kuwahara Shunsuke, Habata Yoichi |
概要 | Tetra-armed cyclen ( 1 ) bearing two 4-(4'-pyridyl)benzyl and two 3,5-difluorobenzyl groups and its Ag + complexes were prepared and structurally characterized. The complex formed between 1 and Ag + undergoes a reversible structural transformation between a 2:2 dimeric complex and a 3:5 pentacyclic trefoil complex with changes in the Ag + / 1 molar ratio. It was also revealed that the 3:5 trefoil complex could encapsulate benzene and benzene- d 6 selectively in solid-state. The benzene-included structures are stabilized by C-H···F-C interactions between the benzene molecule and the ligand molecule. |
DOI | 10.1002/anie.202010436 |
ISSN | 1521-3773 |
PMID | 32959445 |