イケダ マリ
Mari Ikeda
池田 茉莉 所属 千葉工業大学 工学部 教育センター(工学部) 職種 教授 |
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言語種別 | 英語 |
発行・発表の年月 | 2020/08 |
形態種別 | 学術雑誌 |
標題 | Argentivorous Molecules Exhibiting Highly Selective Silver(I) Chiral Enhancement. |
執筆形態 | 共著 |
掲載誌名 | Inorganic chemistry |
掲載区分 | 国外 |
出版社・発行元 | American Chemical Society |
巻・号・頁 | 59(18),pp.13435-13441 |
著者・共著者 | Lee Eunji, Okazaki Chizuko, Tenma Honoka, Hosoi Yasuhiro, Ju Huiyeong, Ikeda Mari, Kuwahara Shunsuke, Habata Yoichi |
概要 | We report the synthesis of chiral tetra-armed cyclens, having an asymmetric center at one side-arm, that show selective chiral enhancement with silver(I). When the chiral ligand forms a silver(I) complex, the side-arms cover the silver(I) incorporated into the cyclen. The asymmetric center controls the conformation of the side-arms in one direction, increasing the molar ellipticity of the CD spectrum. Chiral cyclens substituted with biphenyl groups exhibit large molar ellipticity values with strong exciton coupling effects. |
DOI | 10.1021/acs.inorgchem.0c01819 |
ISSN | 1520-510X |
PMID | 32857508 |