カサシマ ヨシオ   YOSHIO KASASHIMA
  笠嶋 義夫
   所属   千葉工業大学  創造工学部 教育センター(創造工学部)
   職種   教授
言語種別 英語
発行・発表の年月 2007/04
形態種別 学術雑誌
査読 査読あり
標題 Diastereoselective photocycloaddition using memory effect of molecular chirality by crystallization
執筆形態 共著
掲載誌名 Chemical Communications
出版社・発行元 The Royal Society of Chemistry
巻・号・頁 (16),pp.1632-1634
著者・共著者 Masami Sakamoto, Atsushi Unosawa, Shuichiro Kobaru, Yasuhiro Hasegawa, Takashi Mino, Yoshio kasashima, Tsutomu Fujita
概要 Naphthamides derived from L-proline, which exist as a mixture of several diastereomers in solution, converged to signal diastereomer by crystallization, and the confirmational transformation was contraolled after the crystals were dissolved in the solvent at low temperature, where the fozenconformation was retained long enough for subsequent asymmetric reaction.