カサシマ ヨシオ   YOSHIO KASASHIMA
  笠嶋 義夫
   所属   千葉工業大学  創造工学部 教育センター(創造工学部)
   職種   教授
言語種別 英語
発行・発表の年月 2013/05
形態種別 学術雑誌
査読 査読あり
標題 Asymmetric transformation by dynamic crystallization of achiral succinimides
執筆形態 共著
掲載誌名 Chemical Communications
掲載区分国外
出版社・発行元 Royal Society of Chemistry ( RSC )
巻・号・頁 49(42),pp.4776-4778
著者・共著者 Shoko Hachiya, Yoshio Kasashima, Fumitoshi Yagishita, Takashi Mino, Hyuma Masu and Masami Sakamoto
概要 Optically active materials could be generated by simple solidification of achiral materials without an external chiral source. When achiral cis-3,4-diphenylsuccinimides were solidified in the presence of a catalytic amount of DBU by evaporating the solvent with stirring, optically active trans-3,4-diphenylsuccinimides were obtained quantitatively with high enantiomeric excesses.
ISSN 1359-7345