シバタ　ミツヒロ   SHIBATA MITSUHIRO   柴田　充弘    所属   千葉工業大学  工学部 応用化学科    千葉工業大学  工学研究科 工学専攻    千葉工業大学  工学研究科 応用化学専攻    職種   教授
言語種別	英語
発行・発表の年月	2012/06
形態種別	学術雑誌
査読	査読あり
標題	Biodegradable supramolecular composites of poly(epsilon-caprolactone) and low-molecular-weight organic gelators
執筆形態	共著
掲載誌名	Journal of Applied Polymer Science
掲載区分	国外
出版社・発行元	Wiley
巻・号・頁	124(5),pp.4165-4173
著者・共著者	Mitsuhiro Shibata, Katsuyuki Kaneko, Kazuya Hirayama
概要	When a homogeneous hot liquid of polycaprolactone (PCL) with (R)-12-hydroxystearic acid (HSA) or N-carbobenzyloxy-L-isoleucylaminooctadecane (CIA) was gradually cooled to room temperature, the mixture became gelatinous material and then solidified to give a PCL/HSA or PCL/CIA composite. The rheological measurements of the mixtures of PCL with HSA and CIA revealed that the organogels are formed at around 70-50 and 100-73 degree C during the cooling process, respectively. Furthermore, the formation of supramolecular fibrillar networks was confirmed by the microscopic and differential scanning calorimetric analyses. The tensile moduli of both the composites were improved by the addition of CIA and HSA. Both the composites showed so high biodegradability as PCL did. The fibrillar networks of the composites were also regenerated during the repeated cooling process from the isotropic liquid.
DOI	10.1038/pj.2011.87
ISSN	0021-8995