シバタ　ミツヒロ   SHIBATA MITSUHIRO   柴田　充弘    所属   千葉工業大学  工学部 応用化学科    千葉工業大学  工学研究科 工学専攻    千葉工業大学  工学研究科 応用化学専攻    職種   教授
言語種別	英語
発行・発表の年月	2010/11
形態種別	学術雑誌
査読	査読あり
標題	Intermolecular interaction of supramolecular organic-inorganic hybrid composites of sulfonated polystyrene and oligomeric silsesquioxane possessing pyridyl groups
執筆形態	共著
掲載誌名	Polymer
掲載区分	国外
出版社・発行元	Elseveir
巻・号・頁	51(24),pp.5764-5770
著者・共著者	Mitsuhiro Shibata, Ryosuke Horie, Wataru Yoneta
概要	Supramolecular organic-inorganic hybrid composites of pyridyl groups-possessing oligomeric silsesquioxane (PyOSS) with 1,3-propanedisulfonic acid (PDS), 1,5-naphthalenedisulfonic acid (NDS), and poly(4-styrenesulfonic acid) (PSS) were prepared by solution casting method at SO3H/pyridine 1/1. From the FT-IR analysis, the formation of pyridinium cation moiety was confirmed for PDS/PyOSS and NDS/PyOSS, while it could not be elucidated for PSS/PyOSS. As a result of XPS analysis of the newly prepared hybrid composites of PyOSS and sulfonated polystyrenes (SPSx's) with different degrees of sulfonation (x), the formation of pyridinium ion structure was confirmed for SPS23/PyOSS, and the ionic interaction gradually changed to hydrogen bonding interaction with decreasing degree of sulfonation of SPSx. Although Tg of SPSx moiety was little affected by the addition of PyOSS, the transition itself was gradually weaken and was not detected for SPS23/PyOSS.
DOI	10.1016/j.polymer.2010.10.008
ISSN	0032-3861