シバタ ミツヒロ
SHIBATA MITSUHIRO
柴田 充弘 所属 千葉工業大学 工学部 応用化学科 千葉工業大学 工学研究科 工学専攻 千葉工業大学 工学研究科 応用化学専攻 職種 教授 |
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言語種別 | 英語 |
発行・発表の年月 | 2008/02 |
形態種別 | 学術雑誌 |
査読 | 査読あり |
標題 | Thermal and dynamic mechanical properties of organic-inorganic hybrid composites of itaconate-substituted poly(butylene succinate) and methacrylate-substituted polysilsesquioxane |
執筆形態 | 共著 |
掲載誌名 | J. Appl. Polym. Sci. |
出版社・発行元 | John Wiley & Sons |
巻・号・頁 | 107(4),pp.2159-2164 |
著者・共著者 | Takenori Sakuma, Atsushi Kumagai, Naozumi Teramoto, Mitsuhiro Shibata |
概要 | Itaconate-unit-containing poly(butylene succinate) (PBSI) was synthesized by the reaction of 1,4-butanediol, succinic acid, and itaconic acid in a molar ratio of 2.0 : 1.0 : 1.0, and the obtained PBSI was reacted with methacryl-group-substituted polysilsesquioxane
(ME-PSQ) in the presence of benzoyl peroxide (BPO) at 130 degree C to produce PBSI/ME-PSQ hybrids. The hybrids showed a much higher thermal degradation temperature and storage modulus in the rubbery state than the cured PBSI (CPBSI). The thermal degradation temperature and storage modulus of the hybrids increased with increasing ME-PSQ content. The Tg of the hybrid composites, somewhat increased with increasing ME-PSQ content. However, the Tg's of all the hybrids were lower than that of C-PBSI. Although the IR absorption peak related to C=C groups was not detected for C-PBSI, some olefinic absorption peaks remained for all the hybrids. |
DOI | 10.1002/app.27112 |