イケダ マリ   Mari Ikeda   池田　茉莉    所属   千葉工業大学  工学部 教育センター（工学部）    職種   教授
言語種別	英語
発行・発表の年月	2020/08
形態種別	学術雑誌
標題	Argentivorous Molecules Exhibiting Highly Selective Silver(I) Chiral Enhancement.
執筆形態	共著
掲載誌名	Inorganic chemistry
掲載区分	国外
出版社・発行元	American Chemical Society
巻・号・頁	59(18),pp.13435-13441
著者・共著者	Lee Eunji, Okazaki Chizuko, Tenma Honoka, Hosoi Yasuhiro, Ju Huiyeong, Ikeda Mari, Kuwahara Shunsuke, Habata Yoichi
概要	We report the synthesis of chiral tetra-armed cyclens, having an asymmetric center at one side-arm, that show selective chiral enhancement with silver(I). When the chiral ligand forms a silver(I) complex, the side-arms cover the silver(I) incorporated into the cyclen. The asymmetric center controls the conformation of the side-arms in one direction, increasing the molar ellipticity of the CD spectrum. Chiral cyclens substituted with biphenyl groups exhibit large molar ellipticity values with strong exciton coupling effects.
DOI	10.1021/acs.inorgchem.0c01819
ISSN	1520-510X
PMID	32857508