ヨシゴエ　ユウスケ   吉越　裕介    所属   千葉工業大学  工学部 教育センター（工学部）    職種   准教授
言語種別	英語
発行・発表の年月	2019/10
形態種別	学術雑誌
標題	Lewis acid-catalyzed synthesis of silafluorene derivatives from biphenyls and dihydrosilanes via a double sila-Friedel-Crafts reaction.
執筆形態	共著
掲載誌名	Chemical Communications
掲載区分	国外
巻・号・頁	55(88),pp.13303-13306
著者・共著者	Yafang Dong, Yuta Takata, Yusuke Yoshigoe, Kohei Sekine, Yoichiro Kuninobu
概要	The synthesis of silafluorene derivatives from aminobiphenyl compounds and dihydrosilanes via a double sila-Friedel-Crafts reaction using a borane catalyst has been achieved. This method is applicable to the synthesis of a variety of silafluorene derivatives, such as multisubstituted silafluorenes, spirosilabifluorenes, and silicon-bridged terphenyl compounds, which are not readily obtained using conventional synthetic methods. In addition, we have demonstrated the transformation of the amino groups in these silafluorene derivatives into other substituents.
DOI	10.1039/c9cc07692a
ISSN	1364-548X
PMID	31626267