ヨシゴエ　ユウスケ   吉越　裕介    所属   千葉工業大学  工学部 教育センター（工学部）    職種   准教授
言語種別	英語
発行・発表の年月	2025/03
形態種別	学術雑誌
査読	査読あり
標題	Synthesis and Properties of [3]Rotaxanes with Two Oligo(para-phenylene) Axles.
執筆形態	共著
掲載誌名	Chemistry-A European Journal
掲載区分	国外
巻・号・頁	pp.e202500522
著者・共著者	Misuzu Ohta, Ayano Okuda, Kayori Takahashi, Shoichi Hosoya, Yusuke Yoshigoe, Shinichi Saito
概要	Oligo(para-phenylene) (PPn) is a π-conjugated compound where phenylene units are directly connected at the 1,4-positions. Utilizing the catalytic activity of the macrocyclic dihydrodibenzophenanthroline-Ni complex, we succeeded in the synthesis of [3]- and [2]rotaxanes with PPn axles by biaryl coupling. The size of the macrocycle was critical to synthesize [3]rotaxanes, which consist of two oligo(para-phenylene) axles, in good yields. The relationship between the length of the PPn structure on the 1H NMR spectra of the rotaxanes was studied. The aggregation of a PP8 derivative was suppressed by the presence of the macrocycle in the rotaxanes. A [3]rotaxane could be considered as a model compound of an aggregated PPn, and the photophysical studies disclosed the influence of the aggregation on the properties of PPn.
DOI	10.1002/chem.202500522
ISSN	1521-3765
PMID	40051374