ヨシゴエ　ユウスケ   Yoshigoe Yusuke   吉越　裕介    所属   千葉工業大学  工学部 教育センター（工学部）    職種   准教授
言語種別	日本語
発行・発表の年月	2023/03
形態種別	学術雑誌
査読	査読あり
標題	Copper-Catalyzed Borylation of Styrenes by 1,8-Diaminonaphthalene-Protected Diboronic Acid.
執筆形態	共著
掲載誌名	Organic letters
掲載区分	国外
巻・号・頁	25(12),2093-2097頁
著者・共著者	Taiga Yasuda, Yusuke Yoshigoe, Shinichi Saito
概要	We report a concise synthesis of 1,8-diaminonaphthalene-protected diboronic acid (B2(dan)2), which is a promising borylating agent. B2(dan)2 is a bench-stable compound, and it could be utilized for Cu-catalyzed borylation of styrene derivatives. The reaction proceeded in a highly selective manner, and the products were isolated in up to 97% yields. Mechanistic studies revealed that a borate species would be a key intermediate for the borylation reaction.
DOI	10.1021/acs.orglett.3c00451
ISSN	1523-7052
PMID	36947669